Download Actinide Nanoparticle Research by Horst Geckeis, Thomas Rabung, Thorsten Schäfer (auth.), PDF

By Horst Geckeis, Thomas Rabung, Thorsten Schäfer (auth.), Stepan N. Kalmykov, Melissa A. Denecke (eds.)

ISBN-10: 3642114318

ISBN-13: 9783642114311

This is the 1st booklet to hide actinide nano learn. it truly is of curiosity either for basic examine into the chemistry and physics of f-block components in addition to for utilized researchers corresponding to these learning the long term safeguard of nuclear waste disposal and constructing remediation concepts. The authors hide vital problems with the formation of actinide nano-particles, their houses and constitution, environmental habit of colloids and nanoparticles concerning the secure disposal of nuclear wastes, modeling and complicated tools of characterization on the nano-scale.

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Langmuir 19(11), 4836–4847. Honeyman B. D. (1999) Colloidal culprits in contamination. Nature 397, 23–24. , Mitchell S. , Bickmore B. , and Geckeis H. (2009) Sorption of Cm(III) and Gd(III) onto gibbsite, alpha-Al(OH)(3): A batch and TRLFS study. Journal of Colloid and Interface Science 332(1), 158–164. , Geckeis H. (2010) A comparative batch sorption and time-resolved laser fluorescence spectroscopy study on the sorption of Eu(III) and Cm(III) on synthetic and natural kaolinite. Radiochim. Acta, 98, 613–620.

Yun J. , Marquardt C. , and Fangh€anel T. (2007b) Solubility and redox reactions of Pu(IV) hydrous oxide: Evidence for the formation of PuO2+x(s, hyd). Radiochimica Acta 95(4), 193–207. Neretnieks I. (2006) Flow and transport through a damaged buffer - exploration of the impact of a cemented and an eroded buffer, pp. 43. SKB Technical Report 06-33, Svensk K€arnbr€anslehantering AG, Stockholm, Sweden. Neretnieks I. and Liu J. (2006) Physical and chemical stability of the bentonite buffer. SKB Technical Report 06-103, Svensk K€arnbr€anslehantering AG, Stockholm, Sweden.

The metal cations behave structurally similar to Al and thus become incorporated into a stable colloid-borne species. This could be very relevant in natural aquifer systems, in which colloids, including aluminosilicate colloids, are always present. Aquatic colloids, such as aluminosilicate colloids may therefore facilitate the migration of trivalent actinides as colloidborne species, with little interaction on geomatrices surfaces. Actinide incorporation into colloid structure has been observed in repository relevant ground water mixing zones as discussed above (Kunze et al.

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